Lattice relaxation effects on the collective resonance spectra of a finite dipole array

Phys Chem Chem Phys. 2023 Apr 5;25(14):10054-10062. doi: 10.1039/d3cp00195d.

Abstract

Dielectric/plasmonic lattice relaxation spectroscopy is theoretically discussed in this work. A lattice relaxation effect generally occurs in nanocrystals, which means that from the bulk phase to the crystal surface, lattice parameters show a gradual shift. Here, lattice relaxation is introduced into finite polarizable point arrays or rod arrays as an adjusting tool, and its effect on lattice resonance extinction spectrum peaks is calculated. DDA (discrete dipole approximation) and FDTD (finite difference time domain) methods are applied. Different from an ideal infinite array, a finite array exhibits a broad, rippled extinction spectral peak. The application of an expanded/contracted lattice relaxation to the finite array can compress the ripple on one shoulder of the peak, as a cost, and the other shoulder of the peak gets more rippled, showing a "ripple transfer" effect. The strategy introduced in this work can contribute to the micro/nano optical measurement, on-chip adjustable optical cavity for OPOs (optical parameter oscillators)/lasers and controlling of fluorescence or hot-electron chemistry.