Molybdenum disulfide co-catalysis boosting nanoscale zero-valent iron based Fenton-like process: Performance and mechanism

Abstract

The conventional Fenton process has the drawbacks of low efficiency of Fe³⁺/Fe²⁺ conversion, low utilization of H₂O₂, and narrow range of pH. In this paper, molybdenum sulfide (MoS₂) was used as a co-catalyst to boost the nanoscale zero-valent iron (nZVI) based heterogeneous Fenton-like process for the degradation of Rhodamine B (RhB). The catalytic performance, influences of parameters, degradation mechanism, and toxicity of intermediates were explored. Compared with the conventional like-Fenton process, the existence of MoS₂ accelerated the decomposition of H₂O₂ and the RhB degradation rate constant of MoS₂/nZVI/H₂O₂ reached more than six times that of nZVI/H₂O₂. In addition, the effective pH range of MoS₂/nZVI/H₂O₂ was broadened to 9.0 with 84.9% of RhB being removed within 15 min. The co-catalytic system of MoS₂ and nZVI was stable and had high reusability according to the results of four consecutive runs. Quenching tests and electron paramagnetic resonance (EPR) demonstrated that hydroxyl radical (·OH), superoxide anions (·O₂^-), and singlet oxygen (¹O₂) were all involved in MoS₂/nZVI/H₂O₂. Compared with nZVI/H₂O₂ system, MoS₂ not only increased the corrosion of nZVI but also accelerated the conversion of Fe³⁺/Fe²⁺. ECOSAR analysis suggested that the overall acute and chronic toxicity of the degradation products decreased after treatment. Hence, this MoS₂ co-catalytic nZVI based Fenton-like process can be used as a promising alternative for the treatment of organic wastewater.

Keywords: Co-catalysis; Fenton-like; Hydrogen peroxide (H(2)O(2)); Molybdenum sulfide (MoS(2)); Nanoscale zero-valent iron (nZVI).