Determination of nitrogen sources and losses in surface runoff from different lands at a watershed scale

Abstract

Nitrogen (N) loss by surface runoff inevitably results in severe N pollution and eutrophication of aquatic ecosystems. In this study, surface runoff from different land uses in the East Tiaoxi River watershed was collected, and the N concentrations, sources and losses were measured using the dual isotope (δ¹⁵N-NO₃^- and δ¹⁸O-NO₃^-), a Bayesian isotopic mixing (SIAR) model and Soil Conservation Service Curve Number (SCS-CN) method. The results showed that the N concentrations in surface runoff from agricultural lands were higher than those from urban areas and forestlands, and nitrate (NO₃^-), particulate nitrogen (PN) and dissolved organic nitrogen (DON) were the major forms of N in surface runoff in the East Tiaoxi River watershed. The total loss rate of total nitrogen (TN) from surface runoff in the East Tiaoxi River watershed was 5.38 kg·ha^-1·a^-1, with NO₃^--N (46%) contributing the most to TN loss. The TN, and NO₃^--N loss rates in surface runoff from tea planting lands (21.08 kg·ha^-1·a^-1, 11.98 kg·ha^-1·a^-1) and croplands (16.93 kg·ha^-1·a^-1, 10.96 kg·ha^-1·a^-1) were high, those from vegetable lands and urban areas were medium, and those from economic and natural forestlands were low in the East Tiaoxi River watershed. The NO₃^--N contributions of chemical fertiliser (CF), soil N (SN), sewage/manure (SM), and atmospheric deposition (AD) in surface runoff in the East Tiaoxi River watershed were 124.32 × 10³, 104.84 × 10³, 82.25 × 10³ and 58.69 × 10³ kg·a^-1, respectively. The N pollutant losses in surface runoff from agricultural lands (croplands with rice growing, vegetable lands and tea planting lands) were responsible for most of the N pollutants being transported into the East Tiaoxi River systems.

Keywords: Isotopes; Nitrogen losses; Nitrogen sources; SCS-CN method; SIAR model; Surface runoff.