A comprehensive photovoltaic study on tungsten disulfide (WS2) buffer layer based CdTe solar cell

E I Emon; A M Islam; M K Sobayel; S Islam; Md Akhtaruzzaman; N Amin; A Ahmed; M J Rashid

doi:10.1016/j.heliyon.2023.e14438

A comprehensive photovoltaic study on tungsten disulfide (WS2) buffer layer based CdTe solar cell

Heliyon. 2023 Mar 11;9(3):e14438. doi: 10.1016/j.heliyon.2023.e14438. eCollection 2023 Mar.

Authors

E I Emon¹, A M Islam¹, M K Sobayel², S Islam³, Md Akhtaruzzaman², N Amin⁴, A Ahmed¹, M J Rashid^{1

5}

Affiliations

¹ Department of Electrical and Electronic Engineering, University of Dhaka, Dhaka 1000, Bangladesh.
² Solar Energy Research Institute, The National University of Malaysia, Bangi 43600, Malaysia.
³ Department of Information and Communication Technology, Bangladesh University of Professionals, Dhaka 1216, Bangladesh.
⁴ Institute of Sustainable Energy, Universiti Tenaga Nasional, Kajang 43000, Selangor, Malaysia.
⁵ Semiconductor Technology Research Center, University of Dhaka, Dhaka 1000, Bangladesh.

Abstract

Transition metal di-chalcogenides (TMCDs)-Tungsten disulfide (WS₂) exhibit excellent optoelectronic properties such as suitable bandgap, high absorption coefficient, good conductivity, high carrier mobility, etc. to be used as a photovoltaic material for thin-film solar cells. In the present work, we have replaced the traditional buffer CdS and ITO/ZnO window layer in CdTe solar cells with the non-toxic, earth-abundant WS₂ buffer and SnO₂ window layer, respectively. The SCAPS-1D solar simulator is used to investigate the potentiality of WS₂ as buffer material in CdTe solar cells. This numerical study provides a comparison of the performances between the proposed structure: SnO₂/WS₂/CdTe/Au and the baseline structure: ITO/ZnO/CdS/CdTe/Au. The impacts of the charge carrier generation rate, spectral response, current-voltage characteristics, bulk defect density, defect density at buffer/absorber interface, operating temperature, and capacitance-voltage characteristics on the solar cell performance parameters have also been analyzed. The tolerance level of defect density in WS₂ bulk and WS₂/CdTe interface are found to be 10¹⁷ cm^-3 and 10¹² cm^-3, respectively. The temperature study reveals the poor structural robustness and thermal stability of the proposed cell. The conversion efficiency of the proposed cell has found to be 20.55% at the optimized device structure. Nevertheles, these findings may provide an insight to fabricate viable, environment friendly, and inexpensive CdTe thin-film solar cells.

Keywords: Buffer layer; CdTe Solar cell; Numerical study; Transition metal di-chalcogenides (TMCDs); Tungsten disulfide (WS2).