Solid-contact polymeric membrane ion-selective electrodes using a covalent organic framework@reduced graphene oxide composite as ion-to-electron transducer

Wenting Zhang; Jinghui Li; Wei Qin

doi:10.1016/j.talanta.2023.124444

Solid-contact polymeric membrane ion-selective electrodes using a covalent organic framework@reduced graphene oxide composite as ion-to-electron transducer

Talanta. 2023 Jun 1:258:124444. doi: 10.1016/j.talanta.2023.124444. Epub 2023 Mar 11.

Authors

Wenting Zhang¹, Jinghui Li², Wei Qin³

Affiliations

¹ College of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong, 264005, PR China; CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences (CAS), Shandong Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai, Shandong, 264003, PR China.
² CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences (CAS), Shandong Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai, Shandong, 264003, PR China. Electronic address: jinghuili@yic.ac.cn.
³ CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research (YIC), Chinese Academy of Sciences (CAS), Shandong Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai, Shandong, 264003, PR China; Qingdao National Laboratory for Marine Science and Technology, Qingdao, Shandong, 266237, PR China; Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao, Shandong, 266071, PR China. Electronic address: wqin@yic.ac.cn.

PMID: 36934662
DOI: 10.1016/j.talanta.2023.124444

Abstract

A solid-contact ion-selective electrode (SC-ISE) based on a covalent organic framework@reduced graphene oxide (rGO) composite is proposed. The composite can be synthesized through the polycondensation of 1,3,5-triformylphloroglucinol (TFP) and 2,6-diaminoanthraquinone (DAAQ) on the rGO nanosheets, which shows high capacitance and good redox-active properties. By applying Cd²⁺-ISE as a model, the electrode exhibits a Nernstian slope of 29.7 ± 0.4 mV/decade in the activity range of 1.0 × 10^-7 - 7.9 × 10^-4 M and the limit of detection is 6.8 × 10^-8 M. Particularly, the electrode based on DAAQ-TFP@rGO exhibits a low potential drift of 1.2 ± 0.2 μV/h over 70 h due to the large capacitance of 2.0 mF. Moreover, the DAAQ-TFP@rGO-based Cd²⁺-ISE shows good reproducibility and the standard deviations of the standard potentials for single batch and batch-to-batch are 0.28 (n = 4) and 0.30 mV (n = 4), respectively. The developed SC-Cd²⁺-ISE is not disturbed by light or gas and no aqueous layer occurs between the sensing membrane and DAAQ-TFP@rGO layer. The DAAQ-TFP@rGO composite is highly promising for construction of calibration-free SC-ISEs.

Keywords: Covalent organic framework; Ion-selective electrode; Reproducibility; Solid contact; Stability.