A review on multi-synergistic transition metal oxide systems towards arsenic treatment: Near molecular analysis of surface-complexation (synchrotron studies/modeling tools)

Abstract

The science and interface chemistry between the arsenic (As) anions and the different adsorbent systems have been gaining interest in recent years in environmental remediation applications. Metal-oxides and the corresponding hybrid systems have shown promising performance as novel adsorbents in various treatment technologies. The abundance, surface chemistry, high surface area (active-centres), various synthesis and functionalization methodologies, and good recyclability make these metal oxide-based nanomaterials as potential remediating agents for As oxyanions. This work critically reviews eight different platforms focused on the arsenic contamination issue, where the first classification describes the origin of arsenic contamination and presents geographical and demo-graphical considerations. The following section briefs the state-of-the-art remediation techniques for arsenic treatment with a comparative evaluation. An emphasized discussion has been provided regarding the adsorption and classification of various metal oxide adsorbents. In the next classification, various multi-synergism abilities like Redox activity, Surface functional groups, Surface area/morphology, Heterogeneous catalysis, Reactive oxygen species, Photo-catalytic/electro-catalytic reactions, and Electrosorption are detailed. The classification of various characterization tools for accessing the arsenic remediation qualitatively and quantitatively are given in the fifth chapter. The first-of-its-kind dedicated analysis has been given on the surface complexation aspects of the arsenic speciation onto various metal adsorbent systems using synchrotron results, surface-complexation modeling, and molecular simulation (e.g., DFT) in the sixth chapter. The current sensing applications of these novel nano-material systems for arsenic determination using colorimetric and electrochemical-based analytical tools and a note about the economic parameters, i.e., regeneration aspects of various adsorbent systems/the sustainable applications of the treated sludge materials, are provided in the final sections. This work makes a critical analysis of 'Environmental Nanotechnology' towards 'Arsenic Treatment'.

Keywords: Adsorption; Arsenic; Materials chemistry; Multi-synergism; Surface-complexation; Sustainability Aspects; Synchrotron studies (XAS).