1ReH•Cl, a highly robust and antiaromatic rhenium(I) complex of triarylrosarin, is synthesized. The 1H NMR spectrum of 1ReH•Cl shows upfield-shifted pyrrole protons and highly downfield-shifted inner protons that confirm its antiaromatic nature, with density functional theory calculations strongly supporting this interpretation. Antiaromatic 1ReH•Cl absorbs from the UV to near-IR region of the optical spectrum; cyclic voltammetry, thin-layer UV-vis spectroelectrochemistry, and spin-density distributions clearly reveal that the rosarin backbone of 1ReH•Cl undergoes redox chemistry. The X-ray structure of 1ReH•Cl shows a fully coordinated and protonated inner cavity that effectively prevents proton-coupled electron transfer when treated with an acid. A remarkably negative NICS(0) value, clockwise anisotropy of the induced current density ring current, and the aromatic shielded inner cavity in the 2D ICSS(0) map reveal that the T1 state of 1ReH•Cl is aromatic based on Baird's rule.