Exploring the influence mechanism of water grinding on the gel properties of corn starch based on changes in its structure and properties

J Sci Food Agric. 2023 Aug 15;103(10):4858-4866. doi: 10.1002/jsfa.12554. Epub 2023 Mar 28.

Abstract

Background: At present, most studies have focused on the preparation of modified starches by dry grinding. As an excellent starch plasticizer, water might enhance the action of grinding on the structure of starch granules, and water grinding might improve the gel properties of starch. Therefore, this article explored the influence mechanism of water grinding on the gel properties of corn starch based on the changes in its structure and properties.

Results: The results showed that water grinding could make water enter the starch granules and hydrate the starch molecules, and the starch gelatinized after water grinding for 20 min. Thus, water enhanced the action of grinding on the structure of the starch granules. Under the plasticization and grinding action of water grinding, the mechanochemical effect of the starch granules occurred. When the starch was in the aggregation stage (7.5-10 min), the crystallinity of the starch increased, and the starch molecules rearranged into a more stable structure, which increased apparent viscosity (η), elastic modulus (G') and viscous modulus (G″) of the starch gels.

Conclusion: Therefore, appropriate water grinding (10 min) contributed to increasing the viscoelasticity of starch gels. This study provided a theoretical foundation for research on improving the properties of starch by mechanical modification in future. © 2023 Society of Chemical Industry.

Keywords: corn starch; gel properties; structure; water grinding.

MeSH terms

  • Elastic Modulus
  • Gels / chemistry
  • Starch* / chemistry
  • Viscosity
  • Zea mays* / chemistry

Substances

  • Starch
  • Gels