As anode material for sodium ion batteries (SIBs), biomass-derived hard carbon has attracted a great deal of attention from researchers because of its renewable nature and low cost. However, its application is greatly limited due to its low initial Coulomb efficiency (ICE). In this work, we employed a simple two-step method to prepare three different structures of hard carbon materials from sisal fibers and explored the structural effects on the ICE. It was determined that the obtained carbon material, with hollow and tubular structure (TSFC), exhibits the best electrochemical performance, with a high ICE of 76.7%, possessing a large layer spacing, a moderate specific surface area, and a hierarchical porous structure. In order to better understand the sodium storage behavior in this special structural material, exhaustive testing was performed. Combining the experimental and theoretical results, an "adsorption-intercalation" model for the sodium storage mechanism of the TSFC is proposed.
Keywords: Coulomb efficiency; Na-ion batteries; bio-derived hard carbon; storage mechanism.