Photonic crystal materials based on cellulose nanocrystals (CNC), which are environmentally responsive and green, have attracted widespread attention. To overcome the brittleness of CNC films, many researchers have explored functional additives to improve their performance. In this study, a new green deep eutectic solvents (DESs) and an amino acid-based natural deep eutectic solvents (NADESs) were introduced into CNC suspensions for the first time, and hydroxyl-rich small molecules (glycerol, sorbitol) and polymers (polyvinyl alcohol, polyethylene glycol) were coassembled with the DESs and NADESs to form three-component composite films. The CNC/G/NADESs-Arg three-component film reversibly changed color from blue to crimson as the relative humidity rose from 35 % to 100 %; additionally, the elongation at break increased to 3.05 %, and the Young's modulus decreased to 4.52 GPa. The hydrogen bond network structure provided by trace amounts of the DESs or NADESs not only improved the mechanical properties of the composite films but also increased their water absorption capacities without destroying their optical activities. This allows for the development of more stable CNC films and creates potential for biological applications in the future.
Keywords: Cellulose nanocrystal; Composite film; Humidity; Natural deep eutectic solvents; Optical activity.
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