The highly efficient removal of heavy metals is one of the important factors to evaluate adsorbents. In our study, carbon@chitosan@montmorillonite nanosheet (C@CS@MTN) was successfully prepared via layer-by-layer assembly for the removal of Cu2+ and Cd2+ from solution. High-intensity ultrasound peeling technology was used to release Si-O tetrahedron and Al-O octahedron from montmorillonite in order to exert their optimal adsorption potential. Fourier transform infrared spectroscopy, an X-ray diffractometer, BET surface area measurement, and the inductively coupled plasma emission spectrometry were adopted to investigate the morphology, functional groups, and adsorption capacity of C@CS@MTN. Batch experiment results indicated that both Cu2+ and Cd2+ were effectively removed from solution with the range of pH from 2 to 6. The removal ratio of Cu2+ and Cd2+ onto C@CS@MTN increased with the rise of reaction temperature and their maximum adsorption capacities reached 1108.8 mg·g-1 and 237.4 mg·g-1, respectively, under the condition of the reaction temperature 40 °C, the reaction time 4 h, and the pH = 6. The molecular simulation calculation indicated that there was an obvious electron transfer between Si-O tetrahedron and metal cations, but not for Al-O octahedron. In comparison to Al-O octahedron, the bonding of Cu-O and Cd-O caused the Si-O bond to be broken, resulting in the deconstruction of Si-O tetrahedron and their recombination via the junction of O atoms. It was exactly the deconstruction and recombination of endogenous active units that provide more sites for metal ion adsorption.
Keywords: Binding energy; Electron transfer; Endogenous active units; Heavy metal adsorption; Montmorillonite nanosheet.
© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.