Stable isotope signatures of deuterium, oxygen 18, and carbon 13 (δ2H, δ 18O, δ 13C) in imported apples available in the markets of Vietnam

Food Chem X. 2023 Jan 11:17:100576. doi: 10.1016/j.fochx.2023.100576. eCollection 2023 Mar 30.

Abstract

This study examines whether fresh apples from the United States, New Zealand, and China sold in the markets of Vietnam can be distinguished based on the stable isotopic signatures of their water and carbon (δ2H, δ18O, and δ13C). The δ2H and δ18O in apples from the United States were found to average - 100.1 ‰ and - 10.5 ‰ vs VSMOW, respectively, lighter than those from New Zealand and China. In apples from China, the δ13CVBDP averaged - 25.8 ‰, which is more enriched than apples from the United States and New Zealand. A clear distinction was shown in the δ2H, δ18O, and δ13C values in apple samples from the three regions based on the statistical treatment at a 95 % confidence level and p < 0.05. This method is reliable enough to control the import and export of agricultural products.

Keywords: Apple; CF IRMS; Cryogenic vacuum extraction; Geographical origin; Laser spectrometry; Stable isotope compositions.