A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts

Valery N Zakharov; Pavel S Lemport; Vladimir V Chernyshev; Victor A Tafeenko; Alexandr V Yatsenko; Yuri A Ustynyuk; Sergey F Dunaev; Valentine G Nenajdenko; Leonid A Aslanov

doi:10.3390/molecules28041941

A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts

Molecules. 2023 Feb 17;28(4):1941. doi: 10.3390/molecules28041941.

Authors

Valery N Zakharov¹, Pavel S Lemport¹, Vladimir V Chernyshev¹, Victor A Tafeenko¹, Alexandr V Yatsenko¹, Yuri A Ustynyuk¹, Sergey F Dunaev¹, Valentine G Nenajdenko¹, Leonid A Aslanov¹

Affiliation

¹ Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1 bld. 3, Moscow 119991, Russia.

Abstract

The reaction of pyridine with cyanuric chloride was studied under microwave activation as well as in the presence of silver nitrate. The product of hydrolysis containing two pyridinium rings and chloride anion was isolated. The structures of these anion exchanger salts with chloride, nitrate and perrhenate anions are discussed.

Keywords: 1,3,5-triazine; DFT; NMR; anion exchanger; crystal structure; precipitation of perrhenate.

MeSH terms

Anions / chemistry
Chlorides* / chemistry
Nitrates* / chemistry
Salts
Triazines / chemistry

Substances

Nitrates
Chlorides
perrhenate
Salts
Anions
Triazines

Grants and funding

This research was funded by the Russian Science Foundation (grant no. 21-73-10067).