Serious membrane fouling has limited the development of ultrafiltration membrane technology for water purification. Synthesis of an ultrafiltration membrane with prominent anti-fouling ability is of vital importance. In this study, CAB-GO composite nanosheets were prepared by grafting graphene oxide (GO) with a zwitterionic material cocamidopropyl betaine (CAB) with strong antifouling properties. Anti-fouling CAB-GO/PES mixed matrix ultrafiltration membrane (CGM) was prepared by the phase inversion method with polyethersulfone (PES). Due to its electrostatic interaction, the interlayer distance between CAB-GO nanosheets was increased, and the dispersibility of GO was improved to large extent, thereby effectively avoiding the phenomenon of GO agglomeration in organic solvents. Based on the improvement of the surface porosity and surface hydrophilicity of the CAB-GO/PES mixed matrix membrane, the pure water flux of CGM-1.0 can reach 461 L/(m2·h), which was 2.5 times higher than that of the original PES membrane, and the rejection rates toward BSA and HA were above 96%. Moreover, when the content of CAB-GO was 0.1 wt%, the prepared CAB-GO/PES membrane exhibited very high BSA (99.1%) and HA (98.1%) rejection during long-term operation, indicating excellent anti-fouling ability.
Keywords: antifouling; graphene oxide (GO); mixed matrix ultrafiltration membrane; polyethersulfone (PES); zwitterionic polymer.