Toward a Comprehensive Understanding of Amorphous Photocatalysts: Fundamental Hypotheses and Applications in CO2 Photoreduction

Abstract

In principle, photocatalytic activity can be precisely controlled with crystalline catalysts. However, an amorphous photocatalyst could be a viable candidate for CO₂ photoreduction to form value-added products. The amorphous phase is currently part of the crystalline material in several ongoing CO₂ photoreduction studies. Additionally, no study indicates the amorphous material required for overall CO₂ photoreduction. This perspective review article highlights fundamental assumptions that are necessary to gain insights and understand the effectiveness of amorphous photocatalysts for CO₂ photoreduction. We start with basic ideas and theories about these materials, including light harvesting, variable coordination number, and the interaction of CO₂ molecules with the amorphous catalytic surface. To understand the prospects of the amorphous photocatalyst, we explore machine learning with EXAFS. Furthermore, we discuss product selectivity and regeneration of photocatalysts in detail. Finally, we briefly review the work in progress on amorphous materials and compare it to that on crystalline ones.

Keywords: CO2 reduction; amorphous catalysts; artificial photosynthesis; coordination chemistry; photocatalysis.