Accumulation of high concentration fluoride in the Ulungur Lake water through weathering of fluoride containing rocks in Xinjiang, China

Abstract

Fluoride is a potential contaminant at high concentrations when used for drinking due to its adverse human health effects. The Ulungur Lake in Xinjiang, China has a long history of high fluoride concentration in lake water, but the mechanism leading to such high concentrations of fluoride is still unclear. In this study we evaluate the fluoride concentration in different water bodies and upstream rock formations in the Ulungur watershed. The result show that fluoride concentration in the Ulungur Lake water fluctuates around 3.0 mg L^-1, although the fluoride concentrations in the feeding rivers and groundwater are all lower than 0.5 mg L^-1. A mass balance model is developed for water, fluoride, and total dissolved solid in the lake, and the model explains why the concentration of fluoride in the lake water is higher than those in river and ground water. Bedrock compositions are measured from nearby formations which confirm the potential of these rocks to release fluoride into water bodies through water-rock interactions. The whole-rock concentrations of fluoride are in the range of 0.4-2.4 g kg^-1 and the water-soluble concentrations of fluoride in the upstream rocks are 0.26-3.13 mg L^-1. Biotite and hornblende are identified as the fluorine containing minerals in the Ulungur watershed. The concentration of fluoride in the Ulungur has been declining slowly in recent years due to increased water inflow fluxes, and our mass balance model predicts that the fluoride concentration will eventually reach 1.70 mg L^-1 under a new steady state, but it requires about 25-50 years to reach the new steady state. The yearly fluctuation of fluoride concentration in the Ulungur Lake is likely due to changes in water-sediment interactions reflected in changes in lake water pH.

Keywords: Fluoride concentration; Rock weathering; Ulungur lake water.