A Review of Phosphorus Structures as CO2 Reduction Photocatalysts

Abstract

Effective photocatalytic carbon dioxide (CO₂ ) reduction into high-value-added chemicals is promising to mitigate current energy crisis and global warming issues. Finding effective photocatalysts is crucial for photocatalytic CO₂ reduction. Currently, metal-based semiconductors for photocatalytic CO₂ reduction have been well reviewed, while review of nonmetal-based semiconductors is almost limited to carbon nitrides. Phosphorus is a promising nonmetal photocatalysts with various allotropes and tunable band gaps, which has been demonstrated to be promising non-metallic photocatalysts. However, no systematic review about phosphorus structures for photocatalytic CO₂ reduction reactions has been reported. Herein, the progresses of phosphorus structures as photocatalysts for CO₂ reduction are reviewed. The fundamentals of photocatalytic CO₂ reduction, corresponding properties of phosphorus allotropes, photocatalysts with phosphorus doping or phosphorus-containing ligands, research progress of phosphorus allotropes as photocatalysts for CO₂ reduction have been reviewed in this paper. The future research and perspective of phosphorus structures for photocatalytic CO₂ reduction are also presented.

Keywords: cocatalysts; elemental semiconductors; heterostructures; phosphorus allotrope; photocatalytic CO 2 reduction.