Reduction of natural radioactivity in groundwater with different salinity through adsorption of uranium and radium in filter materials

Environ Sci Pollut Res Int. 2023 Apr;30(17):48988-48998. doi: 10.1007/s11356-023-25638-w. Epub 2023 Feb 10.

Abstract

In many small communities in the Mediterranean area, groundwater is usually the only water body available. Depending mainly on the surrounding geology, their concentration of naturally occurring radionuclides may pose a radiological hazard. Removal of uranium and radium from drinking water is the best way to avoid it, i.e., reverse osmosis (RO), but consuming a lot of energy. Thus, two modified drinking water treatment plants (DWTPs) using zeolites coated with manganese dioxide as adsorbent material were analyzed as an alternative to RO. Groundwater salinity can negatively affect this process. Radium removal decreased as water salinity increased; but it had a major impact on uranium, rendering the adsorption effectless in one DWTP. Waste management and how to avoid it from becoming radioactive are of major concern. Radium and uranium were associated to the reducible fraction in the filter material and also to the carbonate fraction in the case of uranium. Regeneration of the filter material using KCl solutions was able to remove 81% and 63% of uranium and radium, respectively.

Keywords: Adsorption; Catalytic bed; Chemical regeneration; Desorption; Drinking water; Speciation.

MeSH terms

  • Adsorption
  • Drinking Water*
  • Groundwater*
  • Radioactivity*
  • Radium* / analysis
  • Salinity
  • Uranium* / analysis
  • Water Pollutants, Radioactive* / analysis

Substances

  • Radium
  • Uranium
  • Drinking Water
  • Water Pollutants, Radioactive