SnLa2O5 wrapped carboxymethyl cellulose mixed calcium alginate nanocomposite beads for efficient reduction of pollutants

Abstract

In this project, lanthanum oxide doped tin oxide (SnLa₂O₅) nanomaterial was prepared and characterized morphologically and physiochemically by different techniques. The catalytic performance of SnLa₂O₅ was assessed toward catalytic reduction of 4-nitrophenol (4-NP), methyl orange (MO), congo red (CR), methylene blue (MB) and potassium ferricyanide (K₃[Fe(CN)₆]). SnLa₂O₅ was found to be efficient for K₃[Fe(CN)₆] in the presence of NaBH₄, which reduced in only 8.0 min. SnLa₂O₅ was further wrapped in carboxymethyl cellulose mixed calcium alginate (CMC-Alg) hydrogel beads because the powder catalyst cannot be simply recovered from reaction media to recycle and use again. SnLa₂O₅ wrapped CMC-Alg (SnLa₂O₅/CMC-Alg) was assessed for detail analysis of K₃[Fe(CN)₆] reduction. The effect of NaBH₄, K₃[Fe(CN)₆] concentration and amount of catalyst was optimized using SnLa₂O₅/CMC-Alg. The amount of catalyst has positive impact on catalytic reduction of K₃[Fe(CN)₆]. The kinetic study revealed that K₃[Fe(CN)₆] reduction by SnLa₂O₅ and SnLa₂O₅/CMC-Alg was fast, which completed in 8.0 and 4.0 min with rate constant of 0.4283 min^-1 and 0.7461 min^-1, respectively. These findings indicated that the developed SnLa₂O₅/CMC-Alg is best and proficient nanocatalyst for K₃[Fe(CN)₆] reduction. The efficiency along with cost-effective and simple treatment route of the developed nanocatalyst have prospect to compete and replace the reputable commercial catalysts.

Keywords: Nanocatalyst; Pollutant reduction; SnLa(2)O(5)/CMC-Alg.