Selective Control of Novel TiO2 Nanorods: Excellent Building Blocks for the Electron Transport Layer of Mesoscopic Perovskite Solar Cells

You Jin Park; Young In Jeon; In Seok Yang; Hyunsue Choo; Woo Seok Suh; So-Yeon Ju; Hui-Seon Kim; Jia Hong Pan; Wan In Lee

doi:10.1021/acsami.2c21731

Selective Control of Novel TiO₂ Nanorods: Excellent Building Blocks for the Electron Transport Layer of Mesoscopic Perovskite Solar Cells

ACS Appl Mater Interfaces. 2023 Feb 8. doi: 10.1021/acsami.2c21731. Online ahead of print.

Authors

You Jin Park¹, Young In Jeon¹, In Seok Yang¹, Hyunsue Choo¹, Woo Seok Suh¹, So-Yeon Ju¹, Hui-Seon Kim¹, Jia Hong Pan², Wan In Lee¹

Affiliations

¹ Department of Chemistry and Chemical Engineering, Inha University, Incheon 22212, Korea.
² MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China.

PMID: 36752619
DOI: 10.1021/acsami.2c21731

Abstract

Novel TiO₂ nanorods (NRs) with various lengths of 70-200 nm and uniform widths of 46-48 nm are selectively synthesized by a solvothermal reaction under a basic environment. The length of TiO₂ NRs is reproducibly tuned by varying the concentration of tetramethylammonium hydroxide (TMAH), while the NRs in the pure anatase phase are grown in the [001] direction, caused by the preferential binding affinity of TMAH to the TiO₂ (101) facet. TiO₂ NRs of various lengths are then applied to form the electron transporting layer (ETL) of mesoscopic perovskite solar cells (PSCs). We found that PSC devices with NRs exhibit superior photovoltaic (PV) performance to those with conventional 46 nm-sized TiO₂ nanoparticles (NP46). Particularly, the PSC with TiO₂ NRs of 110 nm length (NR110) exhibits the optimum PV conversion efficiency (PCE): the average PCE is 22.64% with a V_OC of 1.137 V, a J_SC of 24.60 mA·cm^-2, and a FF of 80.96%, while the champion PCE is 23.18%. In addition, the PSC with NR110 (PSC-NR110) reveals significantly improved long-term stability in air with a relative humidity of 40-50%. In 1000 h, its PCE is reduced by only 9% whereas that of PSC with NP46 decreases by 25%. The PSC properties analyzed by impedance spectroscopy and J-V curve measurements under dark conditions and at various light intensities provide evidence that PSC-NR110 has fewer defects and shows significantly reduced charge recombination. We discuss the advantages of NR structures in preparing the ETL of PSC devices and also explain why the charge recombination is suppressed.

Keywords: TiO2 nanorod; electron transporting layer; hydrothermal reaction; perovskite solar cell; pore size control of m-TiO2 layer; solvothermal reaction.