Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS

Bei Jiang; Meilin Li; Shuoang Cao; Zining Wang; Lijun Huang; Xinyi Song; Yuanqiao Zhang; Quanping Yuan

doi:10.1021/acsomega.2c06607

Anisotropic Wooden Electromechanical Transduction Devices Enhanced by TEMPO Oxidization and PDMS

ACS Omega. 2023 Jan 20;8(4):3945-3955. doi: 10.1021/acsomega.2c06607. eCollection 2023 Jan 31.

Authors

Bei Jiang^{1

2}, Meilin Li^{1

2}, Shuoang Cao^{1

2}, Zining Wang^{1

2}, Lijun Huang^{1

2}, Xinyi Song^{1

2}, Yuanqiao Zhang^{1

2}, Quanping Yuan^{1

2}

Affiliations

¹ School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
² MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials & Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, Guangxi University, Nanning 530004, China.

Abstract

In order to increase the number and contact probability of electric dipole on cellulose, acid and alkali treatment was employed to extract hemicellulose and lignin from original wood to gain a highly oriented cellulose frame. The combined means with 2,2,6,6-tetramethylpiperidine-1-oxyl-NaBr-NaClO oxidation and impregnation of PDMS with compression was subsequently used to enhance its mechanical performance and electromechanical conversion. The assembled wooden electromechanical device (10 mm × 10 mm × 1 mm) exhibits the maximum open-circuit voltage (V _OC) of 11.75 V and short-circuit current (I _SC) of 211.01 nA as stepped by foot. It can be sliced to fabricate a flexible sensor with high sensitivity displaying V _OC of 2.88 V and I _SC of 210.09 nA under the tapped state. Its highly oriented wood fiber makes it display significant anisotropy in terms of mechanical and electromechanical performance for multidirectional sense. This strategy will exactly provide reference for developing other high-performance piezoelectric devices.