The Lafayette River comprises a tidal sub-estuary constrained by an urban watershed that is bounded by residential areas at its upper reaches and port activity at its mouth. We determined the concentrations and distributions of polycyclic aromatic hydrocarbons (PAHs) and aliphatic n-alkanes across 19 sites from headwaters to river mouth in surface sediments (0-2 cm). Potential atmospheric sources were investigated through the analysis of wet and dry deposition samples and intact coals from a major export terminal nearby. The potential consequences for human consumption were examined through analysis of native oyster (Crassostrea virginica) and blue crab tissues (Callinectes sapidus). A suite of up to 66 parent and alkyl-substituted PAHs were detected in Lafayette sediments with total concentrations ranging from 0.75 to 39.00 µg g-1 dry wt. Concentrations of aliphatic n-alkanes (n-C16 - n-C31) ranged from 4.94 to 40.83 μg g-1 dry wt. Source assignment using diagnostic ratios and multivariate source analysis suggests multiple sources contribute to the hydrocarbon signature in this metropolitan system with automotive and atmospheric transport of coal dust as the major contributors. Oyster tissues showed similar trends as PAHs observed in sediments indicating similar sources to water column particles which ultimately accumulate in sediments with crabs showing altered distributions as a consequence of metabolism.
Keywords: Atmospheric Deposition; Coal; Estuary; Hydrocarbons; PAHs; Sediments.
© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.