Efficiently photocatalysis activation of peroxydisulfate by Fe-doped g-C3N5 for pharmaceuticals and personal care products degradation

Abstract

Peroxydisulfate (PDS) based advanced oxidation processes (AOPs) are widely used for the degradation of pharmaceutical and personal care products (PPCP) in wastewater treatment. In this study, a Fe-doped g-C₃N₅ (Fe@g-C₃N₅) was synthesized as a photocatalyst for catalyzing the PDS-based AOPs to degrade tetracycline hydrochloride (TH) at pH 3 and Naproxen (NPX) at pH 7. The photocatalytic performance of Fe@g-C₃N₅ was 19% and 67% higher than g-C₃N₅ and g-C₃N₄ for degradation of TH at pH 3, respectively, while it was 21% and 35% at pH 7. The Fe:N ratio in Fe@g-C₃N₅, was calculated as 1:3.79, indicating that the doped Fe atom formed a FeN₄ structure with an adjacent two-layer graphite structure of g-C₃N₅, which improved the charge separation capacity of g-C₃N₅ and act as a new reaction center that can efficiently combine and catalyze the PDS to radicals. Although the intrinsic photo-degradation performance is weak, the photocatalytic performance of Fe@g-C₃N₅ has great room for the improvement and application in wastewater treatment.

Keywords: AOPs; Fe doped g-C(3)N(5); PPCP; Peroxydisulfate; Photocatalysis.