A hexagon based Mn(II) rod metal-organic framework - structure, SF6 gas sorption, magnetism and electrochemistry

Francoise M Amombo Noa; Ocean Cheung; Michelle Åhlén; Elisabet Ahlberg; Priyanka Nehla; Germán Salazar-Alvarez; Soheil Ershadrad; Biplab Sanyal; Lars Öhrström

doi:10.1039/d2cc06916d

A hexagon based Mn(II) rod metal-organic framework - structure, SF₆ gas sorption, magnetism and electrochemistry

Chem Commun (Camb). 2023 Feb 16;59(15):2106-2109. doi: 10.1039/d2cc06916d.

Authors

Francoise M Amombo Noa¹, Ocean Cheung², Michelle Åhlén², Elisabet Ahlberg³, Priyanka Nehla², Germán Salazar-Alvarez², Soheil Ershadrad⁴, Biplab Sanyal⁴, Lars Öhrström¹

Affiliations

¹ Chemistry and Biochemistry, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg SE-41296, Sweden. mystere@chalmers.se.
² Department of Materials Science and Engineering, Ångström Laboratory, Uppsala University, Uppsala SE-751 03, Sweden.
³ Department of Chemistry & Molecular Biology, University of Gothenburg, Gothenburg 405 30, Sweden.
⁴ Department of Physics & Astronomy, Uppsala University, Box-516, Uppsala 75120, Sweden.

PMID: 36723213
DOI: 10.1039/d2cc06916d

Abstract

A manganese(II) metal-organic framework based on the hexatopic hexakis(4-carboxyphenyl)benzene, cpb^6-: [Mn₃(cpb)(dmf)₃], was solvothermally prepared showing a Langmuir area of 438 m² g^-1, rapid uptake OF sulfur hexafluoride (SF₆) as well as electrochemical and magnetic properties, while single crystal diffraction reveals an unusual rod-MOF topology.