Bimetallic FeO x -MO x Loaded TiO2 (M = Cu, Co) Nanocomposite Photocatalysts for Complete Mineralization of Herbicides

Abstract

A series of monometallic and bimetallic cocatalyst(s), comprising FeO _x , CuO _x , CoO _x , FeO _x -CuO _x , and FeO _x -CoO _x loaded TiO₂ catalysts prepared by the surface impregnation method, were investigated for the photocatalytic mineralization of the widely used four herbicides: 2,4-dichlorophenol (2,4-DCP), 2,4,6-trichlorophenol (2,4,6-TCP), 2,4-dichlorophenoxyacetic acid (2,4-D), and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T). It was found that FeO _x -CoO _x /TiO₂ showed the highest photocatalytic efficiency toward mineralization of selected herbicides. FeO _x -CoO _x /TiO₂ achieves 92% TOC removal in 180 min, representing nearly three time activity of the benchmark PC50 TiO₂. From XPS analysis, FeOOH, CuO, and CoO were determined to be loaded onto the TiO₂ surface. The outstanding photocatalytic performance of the optimized FeO _x -CoO _x /TiO₂ sample for herbicides mineralization is due to an increased charge separation and enhanced hydroxyl radicals production monitored by diverse spectroscopies. Based on the proposed charge transfer mechanism, FeO _x -CoO _x cocatalyst species accelerate the transfer of photogenerated holes on TiO₂, thus facilitating hydroxyl radicals production.