Synthesis of perovskite-type potassium niobate using deep eutectic solvents: A promising electrode material for detection of bisphenol A

Thangavelu Sakthi Priya; Tse-Wei Chen; Shen-Ming Chen; Thangavelu Kokulnathan; Bih-Show Lou; Wedad A Al-Onazi; Amal M Al-Mohaimeed; Mohamed S Elshikh; Jaysan Yu

doi:10.1016/j.chemosphere.2023.137948

Synthesis of perovskite-type potassium niobate using deep eutectic solvents: A promising electrode material for detection of bisphenol A

Chemosphere. 2023 Mar:318:137948. doi: 10.1016/j.chemosphere.2023.137948. Epub 2023 Jan 27.

Authors

Thangavelu Sakthi Priya¹, Tse-Wei Chen², Shen-Ming Chen³, Thangavelu Kokulnathan⁴, Bih-Show Lou⁵, Wedad A Al-Onazi⁶, Amal M Al-Mohaimeed⁶, Mohamed S Elshikh⁷, Jaysan Yu⁸

Affiliations

¹ Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei, Taiwan.
² Department of Materials, Imperial College London, London, SW7 2AZ, United Kingdom.
³ Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei, Taiwan. Electronic address: smchen78@ms15.hinet.net.
⁴ Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei, Taiwan.
⁵ Chemistry Division, Center for General Education, Chang Gung University, Taoyuan 333, Taiwan; Department of Orthopaedic Surgery, New Taipei Municipal TuCheng Hospital, Chang Gung Memorial Hospital, New Taipei City, 236, Taiwan. Electronic address: blou@mail.cgu.edu.tw.
⁶ Department of Chemistry, College of Science, King Saud University, P.O. Box 22452, Riyadh 11495, Saudi Arabia.
⁷ Department of Botany and Microbiology, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
⁸ Well Fore Special Wire Corporation, 10, Tzu-Chiang 7th., Chung-Li Industrial Park, Taoyuan, Taiwan.

PMID: 36716937
DOI: 10.1016/j.chemosphere.2023.137948

Abstract

This study demonstrates a hydrothermal method to prepare perovskite-type potassium niobate (KNbO₃) through deep eutectic solvent (DES), which is further used as an electrode material for the determination of bisphenol A (BPA). The as-synthesized KNbO₃ was systematically characterized by different microscopic and spectroscopic techniques. The KNbO₃-modified electrode demonstrates excellent electrocatalytic activity for BPA compared to the pristine electrode. The enhanced performance of the proposed sensor is attributed to the numerous active sites, large electrochemical surface area, high electrical conductivity, and rapid electron transfer. The fabricated sensor shows a wide detection range (0.01-84.3 μM), a low limit of detection (0.003 μM), a high sensitivity (0.51 μA μM^-1 cm^-2), and good anti-interference abilities towards the BPA detection by linear sweep voltammetry method. Besides, it was successfully applied to determining BPA in food samples, demonstrating good practicability. This design paves a new way to fabricate efficient electrode material for various electrochemical applications using a DES medium.

Keywords: Alkali niobates; Deep eutectic solvent; Electrode material; Food samples.

MeSH terms

Deep Eutectic Solvents*
Electrochemical Techniques* / methods
Electrodes

Substances

bisphenol A
potassium niobate
perovskite
Deep Eutectic Solvents