New Types and Dosages for the Manufacture of Low-Energy Cements from Raw Materials and Industrial Waste under the Principles of the Circular Economy and Low-Carbon Economy

Sergio Martínez-Martínez; Luis Pérez-Villarejo; Dolores Eliche-Quesada; Pedro J Sánchez-Soto

doi:10.3390/ma16020802

New Types and Dosages for the Manufacture of Low-Energy Cements from Raw Materials and Industrial Waste under the Principles of the Circular Economy and Low-Carbon Economy

Materials (Basel). 2023 Jan 13;16(2):802. doi: 10.3390/ma16020802.

Authors

Sergio Martínez-Martínez^{1

2}, Luis Pérez-Villarejo¹, Dolores Eliche-Quesada¹, Pedro J Sánchez-Soto²

Affiliations

¹ Department of Chemical, Environmental and Materials Engineering, University of Jaén, Campus Las Lagunillas s/n, 23071 Jaén, Spain.
² Institute of Materials Science of Sevilla (ICMS), Joint Center of the Spanish National Research Council (CSIC), University of Sevilla, 41092 Sevilla, Spain.

Abstract

The cement manufacturing industry is one of the main greenhouse gas emission producers and also consumes a large quantity of raw materials. It is essential to reduce these emissions in order to comply with the Paris Agreement and the principles of the circular economy. The objective of this research was to develop different types of cement clinker blends using industrial waste and innovative design to produce low-energy cement. Several types of waste have been studied as alternative raw materials. Their main characteristics have been analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD), Attenuated total reflectance Fourier trans-form infrared spectroscopy (ATR-FTIR), thermal analysis (TG-DTG-DSC) and scanning electron microscopy and energy dispersive X-ray spectroscopy analysis (SEM-EDS). The results obtained from the experimental work carried out in this research focused on the study of crude blends for low-energy cement created from industrial waste. The effect of the addition of different industrial waste types, as a substitution for raw materials, in the production of low-energy cement with high dicalcium silicate content has been investigated. Thus, the dosage design has been performed using modified Bogue equations and quality indexes (LSF, AM, and SM). The calculations of both the modified Bogue equations and quality indexes necessitate knowledge of the weight percentages of CaO, SiO₂, Al₂O₃, and Fe₂O₃, determined via XRF. In this theoretical design of the different blends, it has been established that a dicalcium silicate ratio of 60-65 wt % and an LSF of 78-83% as the limit are values common to all of them. The calculation basis for the crude blends has been based on calcined materials. Therefore, the chemical composition was established, following this premise. Thus, it was possible to develop cement clinker blends with compositions of 50 wt % and 100 wt % using industrial wastes. This research has shown that the clinkerization process is one of the main options for the valorization of waste and its consideration for inclusion as a raw material within the circularity of the cement industry's production process. Thus, waste is used as a raw material for the production of a more useful substance, taking into account the fundamental principles of the circular economy.

Keywords: CO2 emissions; belite; circular economy; clinker; construction materials; low-carbon economy; low-energy cements; waste products.

Grants and funding

The support of the European Union and the Spanish Government (Ministry of Universities): this research was supported, in part, through the European Recovery Instrument “Next-Generation EU” (UJAR05MS).