Highly sensitive ethanol gas sensor based on ultrathin nanosheets assembled Bi2WO6 with composite phase

Tongwei Yuan; Zhijun Li; Wenshuang Zhang; Zhenggang Xue; Xiaoqian Wang; Zhiheng Ma; Yu Fan; Jiaqiang Xu; Yuen Wu

doi:10.1016/j.scib.2019.04.014

Highly sensitive ethanol gas sensor based on ultrathin nanosheets assembled Bi₂WO₆ with composite phase

Sci Bull (Beijing). 2019 May 15;64(9):595-602. doi: 10.1016/j.scib.2019.04.014. Epub 2019 Apr 5.

Authors

Tongwei Yuan¹, Zhijun Li², Wenshuang Zhang¹, Zhenggang Xue³, Xiaoqian Wang³, Zhiheng Ma¹, Yu Fan¹, Jiaqiang Xu⁴, Yuen Wu⁵

Affiliations

¹ New Energy and Sensing Technology Laboratory, Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China.
² Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China.
³ Department of Chemistry, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei 230026, China.
⁴ New Energy and Sensing Technology Laboratory, Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China. Electronic address: xujiaqiang@shu.edu.cn.
⁵ Department of Chemistry, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei 230026, China. Electronic address: yuenwu@ustc.edu.cn.

PMID: 36659627
DOI: 10.1016/j.scib.2019.04.014

Abstract

Bismuth tungstate (Bi₂WO₆) has many intriguing properties and has been the focus of studies in a variety of fields, especially photocatalysis. However, its application in gas-sensing has been seldom reported. Here, we successfully synthesized assembled hierarchical Bi₂WO₆ which consists of ultrathin nanosheets with crystalline-amorphous composite phase by a one-step hydrothermal method. X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), and high-resolution transmission electron microscopy (HRTEM) techniques were employed to characterize its composition, morphology, and microstructure. By taking advantage of its unique microstructure, phase composition, and large surface area, we show that the resulting Bi₂WO₆ is capable of detecting ethanol gas with quick response (7 s) and recovery dynamic (14 s), extremely high sensitivity (R_a/R_g = 60.8@50 ppm ethanol) and selectivity. Additionally, it has excellent reproducibility and long-term stability (more than 50 d). The Bi₂WO₆ outperform the existing Bi₂WO₆-based and most of the other state-of-the-art sensing platforms. We not only provided one new member to the field of gas sensor, but also offered several strategies to reconstruct nanomaterials.

Keywords: Assembled structure; Bi(2)WO(6); Composite phase; Ethanol detection; Gas sensor; Nanosheets.