Visible light-mediated CP bond formation reactions

Bao-Gui Cai; Jun Xuan; Wen-Jing Xiao

doi:10.1016/j.scib.2019.02.002

Visible light-mediated CP bond formation reactions

Sci Bull (Beijing). 2019 Mar 15;64(5):337-350. doi: 10.1016/j.scib.2019.02.002. Epub 2019 Feb 10.

Authors

Bao-Gui Cai¹, Jun Xuan², Wen-Jing Xiao³

Affiliations

¹ Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China.
² Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China. Electronic address: xuanjun@ahu.edu.cn.
³ Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China. Electronic address: wxiao@mail.ccnu.edu.cn.

PMID: 36659598
DOI: 10.1016/j.scib.2019.02.002

Abstract

Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the construction new CP bond has therefore gained great interests in synthetic organic chemistry. Because of their intrinsic sustainability and green chemistry character, visible light-induced photoredox catalysis has been widely applied in the construction of new chemical bonds, including the formation of CP bond. In this review, we summarized recent achievements in CP bond formation reactions initiated by visible light-induced photoredox catalysis, which mainly focusing on the discussion of reaction design and the mechanism.

Keywords: CP bond formation; Organophosphorus compounds; Photoredox catalysis; Visible light.

Publication types

Review