Novel MOF shell-derived surface modification of Li-rich layered oxide cathode for enhanced lithium storage

Zhitong Xiao; Jiashen Meng; Qi Li; Xuanpeng Wang; Meng Huang; Ziang Liu; Chunhua Han; Liqiang Mai

doi:10.1016/j.scib.2017.12.011

Novel MOF shell-derived surface modification of Li-rich layered oxide cathode for enhanced lithium storage

Sci Bull (Beijing). 2018 Jan 15;63(1):46-53. doi: 10.1016/j.scib.2017.12.011. Epub 2017 Dec 13.

Authors

Zhitong Xiao¹, Jiashen Meng¹, Qi Li¹, Xuanpeng Wang¹, Meng Huang¹, Ziang Liu¹, Chunhua Han², Liqiang Mai³

Affiliations

¹ State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.
² State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China. Electronic address: hch5927@whut.edu.cn.
³ State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China; Department of Chemistry, University of California, Berkeley, CA 94720, USA. Electronic address: mlq518@whut.edu.cn.

PMID: 36658917
DOI: 10.1016/j.scib.2017.12.011

Abstract

Li-rich layered oxide materials have attracted increasing attention because of their high specific capacity (>250 mAh g^-1). However, these materials typically suffer from poor cycling stability and low rate performance. Herein, we propose a facile and novel metal-organic-framework (MOF) shell-derived surface modification strategy to construct NiCo nanodots decorated (∼5 nm in diameter) carbon-confined Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ nanoparticles (LLO@C&NiCo). The MOF shell is firstly formed on the surface of as-prepared Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ nanoparticles via low-pressure vapor superassembly and then is in situ converted to the NiCo nanodots decorated carbon shell after subsequent controlled pyrolysis. The obtained LLO@C&NiCo cathode exhibits enhanced cycling and rate capability with a capacity retention of 95% after 100 cycles at 0.4 C and a high capacity of 159 mAh g^-1 at 5 C, respectively, compared with those of LLO (75% and 105 mAh g^-1). The electrochemical impedance spectroscopy and selected area electron diffraction analyses after cycling demonstrate that the thin C&NiCo shell can endow LLO with high electronic conductivity and structural stability, indicating the undesired formation of the spinel phase initiated from the particle surface is efficiently suppressed. Therefore, this presented strategy may open a new avenue on the design of high-performance electrode materials for energy storage.

Keywords: Li-rich layered oxide; Lithium-ion battery; MOF shell; Surface modification.