Passive Anti-Icing Performances of the Same Superhydrophobic Surfaces under Static Freezing, Dynamic Supercooled-Droplet Impinging, and Icing Wind Tunnel Tests

ACS Appl Mater Interfaces. 2023 Feb 1;15(4):6013-6024. doi: 10.1021/acsami.2c15253. Epub 2023 Jan 19.

Abstract

Overcoming ice accretion on external aircraft wing surfaces plays a crucial role in aviation, and developing environmentally friendly passive anti-icing surfaces is considered to be a promising strategy. Superhydrophobic surfaces (SHSs) have attracted increasing attention due to their potential advantages of keeping the airframe dry without causing additional aerodynamic losses. However, the passive anti-icing performances of SHSs reported to date varied a lot under different icing test conditions. Therefore, a systematic investigation is necessary to elucidate the icing conditions where SHSs can remain effective and pave the way for SHSs toward practical anti-icing applications. Herein, we designed and fabricated a typical type of SHS featuring dual-scale hierarchical structures with arrayed micromountains (with both spacings and heights of tens of micrometers) covered by single-scale sandy-corrugation-like periodic structures (with both spacings and heights of only several micrometers) (termed SS1). Its anti-icing performances under three representative icing conditions, including static water freezing, dynamic supercooled-droplet impinging, and icing wind tunnel conditions, were comparatively investigated. The SS1 SHS maintained a lower static ice-adhesion strength (<60 kPa even after 50 deicing cycles at temperatures as low as -25 °C), which was attributed to a cumulative cracking effect facilitating the ice detachment. Within the laboratory dynamic icing tests, the SS1 SHSs with micromountain heights of 20-30 μm performed optimally in the antiadhesion of supercooled droplets (at an impinging velocity of 3.4 m/s and temperatures of -5 to -25 °C). In spite of the significant anti-icing performances of the SS1 SHSs in both static and dynamic laboratory tests, they could hardly sustain reliable passive anti-icing performances in harsher icing wind tunnel tests with supercooled droplets impinging their surfaces at velocities of up to 50 m/s at a temperature of -5 °C for 10 min. This study can inspire the development of improved SHSs for achieving satisfactory anti-icing performances in real-aviation conditions.

Keywords: dynamic supercooled-droplet impinging; icing wind tunnel tests; passive anti-icing performances; static water freezing; superhydrophobic surfaces.