Noninvasive and sensitive thermometry is crucial to human health monitoring and applications in disease diagnosis. Despite recent advances in optical temperature detection, the construction of sensitive wearable temperature sensors remains a considerable challenge. Here, a flexible and biocompatible optical temperature sensor is developed by combining plasmonic semiconductor W18O49 enhanced upconversion emission (UCNPs/WO) with flexible poly(lactic acid) (PLA)-based optical fibers. The UCNPs/WO offers highly thermal-sensitive and obviously enhanced dual-wavelength emissions for ratiometric temperature sensing. The PLA polymer endows the sensor with excellent light-transmitting ability for laser excitation and emission collection and high biocompatibility. The fabricated UCNPs/WO-PLA sensor exhibits stable and rapid temperature response in the range 298-368 K, with a high relative sensitivity of 1.53% K-1 and detection limit as low as ±0.4 K. More importantly, this proposed sensor is demonstrated to possess dual function on real-time detection for physiological thermal changes and heat release, exhibiting great potential in wearable health monitoring and biotherapy applications.
Keywords: flexible temperature sensor; heater−thermometer; plasmonic semiconductor; upconversion emission enhancement; wearable health monitoring.