Photoinduced Catalytic Organic-Hydride Transfer to CO2 Mediated with Ruthenium Complexes as NAD+ /NADH Redox Couple Models

Abstract

The catalytic organic-hydride transfer to CO₂ was first achieved through the photoinduced two-electron reduction of the [Ru(bpy)₂ (pbn)]²⁺ /[Ru(bpy)₂ (pbnHH)]²⁺ (bpy=2,2'-bipyridine, pbn=2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine, and pbnHH=2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine) redox couple in the presence of 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH). The active species for the catalytic hydride transfer to carbon dioxide giving formate is [Ru(bpy)(bpy⋅^- )(pbnHH)]⁺ formed by one-electron reduction of [Ru(bpy)₂ (pbnHH)]²⁺ with BI⋅.

Keywords: carbon dioxide; formate; hydride transfer; organic hydride; photoreduction; ruthenium complex.