Induced electric conductivity in organic polymers

Beilstein J Nanotechnol. 2022 Dec 19:13:1551-1557. doi: 10.3762/bjnano.13.128. eCollection 2022.

Abstract

Poly(diphenylene phthalide) (PDP) belongs to the class of carbocyclic organic electroactive polymers, which exhibits electric conductive properties when an external electric field and/or mechanical stress is applied. In this work, the transport properties of thin-film layered lead-PDP-lead structures were experimentally studied in a wide temperature range. At sufficiently high temperatures, the current voltage characteristics are satisfactorily described in terms of the injection model of currents limited by the space charge. At temperatures below ≈8 K, a number of samples exhibit features that can be explained by the effect of induced superconductivity in a thin film of conducting polymer enclosed between two massive superconductors (lead).

Keywords: conducting polymer; superconductivity; thin films.

Grants and funding

The work was supported by the Mirror Lab project between HSE University and Bashkir state pedagogic University. The activity of A.S.G. was supported by the Basic Research program of HSE University.