BRIDGE methodology-based quality standards to assess aquifer chemical status in the southwest Bengal Basin, Bangladesh

Abstract

Assessment of natural background levels (NBLs) of compositional groundwater parameters helps to identify the potential threats to groundwater resources. This study is the first attempt to apply the pre-selection-based BRIDGE (Background cRiteria for the IDentification of Groundwater thrEshold) methodology to calculate the NBLs and threshold values (TVs) of major groundwater constituents in the southwest Bengal Basin, Bangladesh. A database consisting of 78 groundwater samples was used to assess the NBLs and associated TVs of the major groundwater parameters (EC, Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl^-, NO₃^-, SO₄^2-, PO₄^3-, Mn²⁺, and Fe²⁺). NBLs were derived based on 90th and 97.7th percentiles. The status of regional groundwater resources was assessed by applying 90th percentile NBL on a regional dataset (n = 196). Results revealed the "poor" chemical status of shallow aquifers denoting heavy deterioration of the groundwater quality due to anthropogenic interventions. Nitrate contamination and salinization were identified as the major threats to the deep groundwater of the southwest Bengal Basin. Finally, to verify the chemical status of groundwater in a heavily urbanized area, derived TVs were applied throughout the experimental site Khulna. Twenty-five deep groundwater samples were collected for this purpose. Though most of the parameters exhibited "good" chemical status, nitrate demonstrated anthropogenic groundwater contamination in Khulna City. Thus, the developed TVs would provide an early warning system of pollution. On a national scale, it is expected to facilitate the sustainable groundwater management of the country and contribute to achieving the Sustainable Development Goals (SDG) of the United Nations (UN) in Bangladesh.

Keywords: Bengal Basin; Chemical status assessment; Groundwater; Natural background level; Sustainable management; Threshold value.