The main aim of this study was the determination of temperature influence on adsorption mechanisms of anionic poly(acrylic acid) (PAA) and cationic polyethylenimine (PEI) on the surface of activated carbons (AC) obtained via chemical activation of nettle (NE) and sage (SA) herbs. All measurements were performed at pH 3 at three temperature values, i.e., 15, 25 and 35 °C. The adsorption/desorption of these polymers from single and mixed solution of adsorbates was also investigated. The viscosity studies were additionally performed to obtain hydrodynamic radius values characterizing polymeric macromolecules conformation in the solution. These data are very important for the explanation of changes of linear dimensions of polymer chains with the rise of temperature caused by the modification of polymer-solvent interactions. Moreover, the XPS studies for the systems showing the highest adsorbed amounts in the specific temperature conditions were carried out. These were the systems containing PEI, PAA and NE-AC activated carbon at 25 °C. In such a case, the maximum adsorption capacity towards PAA macromolecules from a single solution of adsorbate reaches the value of 198.12 mg/g. Additionally, the thermodynamic parameters including the free energies of adsorption, as well as changes in free enthalpy and entropy were calculated.
Keywords: activated biocarbons; hydrodynamic radius of polymeric coil; poly(acrylic acid); polyethyleneimine; polymers simultaneous removal; temperature effect.