The charge-transfer (CT) excited state of FHCl (F+H-Cl-), generated by the photodetachment of an electron from its precursor anion (FHCl-) by a photon energy of ∼9.5 eV, is a realistic prototype of two bidirectional-coupled reaction pathways, namely the proton-transfer (PT) and electron-transfer (ET) channels, that produce F + HCl and FH + Cl combinations, respectively. The early-time dynamics of the CT was studied via the time-dependent propagations of nuclear wave packets comprising three nonadiabatically coupled electronic states defined within a three-dimensional space. The detailed analyses of the early-time dynamics revealed an interesting phenomenon in which the onset of PT was ∼80 fs earlier than that of ET, indicating that PT dominated ET in this case. A more significant finding was that the proper adjustment of the electronic-charge distribution for the onset of ET was obtained ∼80 fs after the onset of PT; this adjustment was mediated by the initial movement of the H atom, i.e., the F-H vibration mode. To avail experimental observables, the branching ratio, χ = PT/(PT + ET), and absorption spectrum generating the neutral FHCl molecule from its precursor anion were also simulated. The results further demonstrated the dependences of the χs and spectrum on the change in the initial vibration level of the precursor anion, as well as the isotopic substitution of the connecting H atom with deuterium, tritium, and muonium.