Nitrogen (N) in sewage sludge (SS) should be reduced if it is to be used to produce clean solid fuels. However, the N transformation during hydrothermal carbonization (HTC) of SS is not yet fully understood. Since the composition of SS is complex, it is wise to study a model compound, which should have typical functional groups of organic components. Hence, in this study, six model components (protein, lipid, cellulose, hemicellulose, humic acid, and lignin) representing the main organic components in SS were mixed with SS and treated at 150-270 °C for 1 h. The influence of the organic component and reaction temperature on hydrochar yield, hydrochar characterization, and N distribution in the products was investigated. Except for proteins and lipids, all the other components were found to contribute to the N content and aromatization of the hydrochar. Humus shows the best comprehensive performance in terms of both reducing the N content and increasing the aromaticity. The strongest effects of hemicellulose and cellulose on N retention in hydrochar are found to occur at 210 °C and 240 °C, respectively. The N retention caused by lignin is correlated with the Mannich reaction at 240 °C, while humus significantly promotes N transformation at 240 °C. For carbohydrates, lignin, and humus, the temperatures required for increasing the N content and aromaticity maintain a high degree of consistency. Although protein pulls down the energy recovery (ER) and yield of the hydrochar, observations indicate that it favors the carbonization process. This finding can be used for estimating the N content and quality of hydrochar and provides references for future research targeting the upgrading of hydrochar.
Keywords: Hydrochar; Hydrothermal carbonization; Nitrogen transformation; Sewage sludge; Solid fuel.
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