We experimentally show that the ballistic length of hot electrons in laser-heated gold films can exceed ∼150 nm, which is ∼50% greater than the previously reported value of 100 nm inferred from pump-probe experiments. We also find that the mean free path of electrons at the peak temperature following interband excitation can reach upward of ∼45 nm, which is higher than the average value of 30 nm predicted from our parameter-free density functional perturbation theory. Our first-principles calculations of electron-phonon coupling reveal that the increase in the mean free path due to interband excitation is a consequence of drastically reduced electron-phonon coupling from lattice stiffening, thus providing the microscopic understanding of our experimental findings.
Keywords: ballistic electrons; density functional perturbation theory; electron−phonon coupling; plasmonics.