Fir sawdust as a low-cost and easily recyclable adsorbent: efficient removal of Pb(II), Cu(II), and Zn(II) contaminants from wastewater

Abstract

The main pollution sources of heavy metals are the arbitrary discharge of industrial wastewater and waste residues, which cause serious harm to the water environment, soil environment, and human health. In this study, following the principle of waste utilization, a gel adsorbent (AA-SW-AMPS) was prepared by microwave-assisted chemical cross-linking using fir sawdust as raw material. A scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and swelling dynamic experiments were used to investigate the microstructure, reaction mechanism, and water absorption performance of AA-SW-AMPS. The N₂ adsorption-desorption curve shows that the porous structure of AA-SW-AMPS creates 240.75 cm²/g of specific surface area to enable excellent heavy-metal sorption. It was determined by adsorption experiments that the optimal adsorption state was when the dosage of AA-SW-AMPS was 5 g/L, the pH of the solution was 5, the adsorption time was 45 min, and the initial heavy metal ion concentration was 250 mg/L. In addition, the adsorption mechanism was investigated using adsorption dynamics, adsorption isotherm, and Materials Studio simulation. The results show that the maximum adsorption capacities of AA-SW-AMPS for Pb(II), Cu(II), and Zn(II) were 253.49 mg/g, 237.29 mg/g, and 232.15 mg/g, respectively, and the adsorption mechanism is monolayer chemisorption. The adsorbent showed great potential in removing heavy metals from wastewater.

Keywords: Adsorbent; Environmental protection; Heavy metals; Simulation; Water environment.