In this paper, we consider the problem of bearing ambiguity in the direction of arrival (DOA) estimation due to spatial aliasing when the minimum wavelength of the processing broadband signal is less than the element spacing of a uniform linear array (ULA). First, an extended frequency-difference (FD) method is presented. Unlike the existing FD methods, the extended FD signal is constructed by conjugate multiplying a diagonal matrix consisting of steering vectors at high frequency and pre-processing direction with the array sampled signal matrix at low frequency. Then, this paper establishes a decision criterion for distinguishing the aliasing component that varies linearly with frequency in the extended FD space. Finally, an unambiguous broadband DOA estimation method is achieved by suppressing spatial aliasing in the extended FD space. The simulation results show the effectiveness of the proposed method in low signal-to-noise ratio, low signal-to-interference ratio, and multi-interference conditions. The unambiguous processing ability of the proposed method is further verified in the South China Sea using ship signals in the frequency band of 200 to 700 Hz and a 10-element ULA with a 6.25 m spacing deployed on the seabed.