Preparation of Oriented ZnO Rod Arrays Using Hexagonal Plate-Like Particles as a Seed Layer

Langmuir. 2023 Jan 10;39(1):487-494. doi: 10.1021/acs.langmuir.2c02734. Epub 2022 Dec 27.

Abstract

ZnO rod film is a promising material for electrodes and sensors due to its large surface area and high electrical conductivity. One of the drawbacks of conventional ZnO rod film is the random orientation of rods. In this study, an oriented ZnO seed layer composed of hexagonal plate-like ZnO particles was prepared by dip-coating. An oriented ZnO rod film was then synthesized by growing this seed layer using a hydrothermal synthesis method. We optimized the concentration of the precursor and the hydrothermal treatment time to synthesize homogeneous ZnO rod arrays. The uniformity of the rod arrays was improved by applying a strong magnetic field (12 T) during hydrothermal treatment.