Rational design of Nd2O3 decorated functionalized carbon nanofiber composite for selective electrochemical detection of carbendazim fungicides in vegetables, water, and soil samples

Abstract

Abuse of carbendazim (CBZ) leaves excessive pesticide residues on agricultural products, which endangers human health because of the residues' high concentrations. Hence, a composite consisting of functionalized carbon nanofibers (f-CNF) with neodymium oxide (Nd₂O₃) was fabricated to monitor CBZ at trace levels. The Nd₂O₃/f-CNF composite-modified electrode displays higher electro-oxidation ability towards CBZ than Nd₂O₃ and f-CNF-modified electrodes. The combined unique properties of Nd₂O₃ and f-CNF result in a substantial specific surface area, superior structural stability, and excellent electrocatalytic activity of the composite yielding enhanced sensitivity to detecting CBZ with a detection limit of 4.3 nM. Also, the fabricated sensor electrode can detect CBZ in the linear concentration range of up to 243.0 μM with high selectivity, appropriate reproducibility, and stability. A demonstration of the sensing capability of CBZ in vegetables, water, and soil samples was reported paving the way for its use in practical applications.

Keywords: Carbendazim; Electroanalysis; Functionalized carbon nanofibers composite; Fungicides detecting sensor; Nd(2)O(3).