FTIR as a Method for Qualitative Assessment of Solid Samples in Geochemical Research: A Review

Molecules. 2022 Dec 13;27(24):8846. doi: 10.3390/molecules27248846.

Abstract

This study aims to collect information about soil investigation by FTIR. As we know, the FTIR technique is most often used in organic and bioorganic chemistry, while in geochemistry FTIR spectroscopy is not used very often. Therefore, there is a problem with the identification and interpretation of the IR spectra of minerals contained in sediments and soils. The reason for this is a deficiency of data about characteristic wavenumbers for minerals. Therefore, this study reviews and sums up, in one place, published articles that are connected to an investigation of minerals from 2002 to 2021 (based on the Scopus database). Additionally, the present review highlights various analytical techniques (ATR-FTIR, DRIFT, 2D-IR, and SR-FTIR) and discusses some of them for geochemical study. Additionally, the study describes helpful tools in the data pre-processing of IR spectra (normalization, baseline correction, and spectral derivatives).

Keywords: 2D-IR; ATR; DRIFT; FTIR; SR-FTIR; geological samples; sediments; soil mineral composition.

Publication types

  • Review

MeSH terms

  • Minerals*
  • Soil*
  • Spectrophotometry, Infrared
  • Spectroscopy, Fourier Transform Infrared / methods

Substances

  • Minerals
  • Soil

Grants and funding

This research received no external funding.