Chloride Diffusion in Concrete Made with Coal Fly Ash Ternary and Ground Granulated Blast-Furnace Slag Portland Cements

Materials (Basel). 2022 Dec 13;15(24):8914. doi: 10.3390/ma15248914.

Abstract

Ternary Portland cement usage with a high amount of cement constituents different from clinker can afford great climate change advantages by lowering the Portland cement clinker content in the final product. This will contribute to cutting greenhouse gas emissions to close to zero by 2050. Such ternary Portland cements can be composed of different amounts of ground granulated blast-furnace slag (GBFS), coal fly ash (CFA), and clinker (K). Cements made with GGBFS, or CFA boast pozzolanic characteristics. Therefore, they would improve both the concrete compressive strength at later ages and durability. The 28- and 90-days mechanical strength test, non-steady state chloride migration test, described in NT BUILD 492, and natural chloride diffusion test (NT BUILD 443) were performed in concrete. Ternary cements made with GBFS and/or CFA presented better chloride diffusion resistance than concrete made with plain Portland cements. Furthermore, the development of compressive strength was delayed. The service life study was developed for concretes made with ternary cements with regard to the chloride penetration case.

Keywords: cement; chloride diffusion; coal fly ash; concrete; durability; granulated blast-furnace slag; recycled materials.

Grants and funding

This work was funded through a Fundación Gómez Pardo grant and also benefited from support through the LOEMCO, a Research Centre of the Technical University of Madrid.