Improving the toughness of diamond composites has become an industrial demand. In this work, Co50Ni40Fe10 multi-element alloy was designed as binder for diamond-based composites prepared by high temperature and high pressure (HTHP). Two methods of mixing-sintering and infiltration-sintering were used to prepare diamond-based composites with different diamond contents. The phase diagrams of Co-C and Co50Ni40Fe10-C at 6 GPa were calculated by Thermo-Calc. The results show that Co50Ni40Fe10 multi-element alloy promotes the sintering of diamond powder than element Co. The transverse rupture strength (TRS) of sintered diamond with Co50Ni40Fe10 (Co50Ni40Fe10-75 vol% diamond) is higher than that of Co-Comp (Co-75 vol% diamond). The TRS of polycrystalline diamond (PCD) with Co50Ni40Fe10 alloy binder is up to 1360.3 MPa, which is 19.2% higher than Co-PCD. Compared with Co, using Co50Ni40Fe10 as binder results in a less metal residue in PCD, while the metal cluster area is smaller and the metal distribution is more uniform.
Keywords: HTHP; PCD; diamond skeleton; multi-element alloy; thermodynamic.