Hydrophobic and oleophilic open-cell foams from in-situ microfibrillation blends of poly(lactic acid) and polytetrafluoroethylene: Selective oil-adsorption behaviors

Abstract

Confronted with severe water contamination induced by the spillage of oils, seeking oil-selective adsorbent to recover oil from oily wastewater is extremely urgent. In particular, the functionalized polymer foams with open-cell structures are highly promising oil-selective adsorbent. Herein, a simple, effective and green method was presented to prepare open-cell poly(lactic acid) (PLA)/polytetrafluoroethylene (PTFE) foams with selective oil-adsorption behaviors via melt blending and supercritical CO₂ batch foaming technique. The introduction of PTFE had a distinct positive influence on the melt viscoelasticity and crystallization performances of various PLA specimens. The resulted PLA/PTFE4 foam with a volume expansion ratio of 10.17 ± 0.93 and a cell density of 1.58 × 10⁸ cells/cm³ possessed the highest open-cell content of 90.81 ± 0.78 %. Meanwhile, PLA/PTFE4 foam revealed oil/water selective adsorption capacity of 1.2-6.1 g/g for various organic solvents and oils. The adsorption capacity of PLA/PTFE4 foam for CCl₄ exhibited no significant decrement during ten adsorption-desorption cycles. This research offered a guideline for the manufacture of green environmental open-cell polymer foams for oil-selective adsorption.

Keywords: Open-cell foam; Poly(lactic acid); Supercritical CO(2) foaming.