Study on the characteristics of radon exhalation from rocks in coal fire area based on the evolution of pore structure

Sci Total Environ. 2023 Mar 1:862:160865. doi: 10.1016/j.scitotenv.2022.160865. Epub 2022 Dec 12.

Abstract

Radon is of great significance as a tracer for the detection of coal fires due to its distinct variations in radon exhalation properties while heating. The research on radon exhalation performance through pore structure is still in its early stages. In this paper, the pore structure and radon exhalation characteristics of heat-treated limestone are studied using indoor tests such as nuclear magnetic and radon measurements. The study's results demonstrate that the radon exhalation rate of limestone initially increases gradually, followed by a steady decline and subsequent increase with the increase in temperature. The radon exhalation rate at 800 °C reaches 2.42 times that at room temperature. The pore structure change within limestone strongly correlates with the radon exhalation rate. The pore volume of micropores (<0.1 μm) plays an essential role in the radon exhalation capacity, which is directly related to the fractal dimension of micropore structure in the heated limestone. The study's findings can be used to identify coal fires.

Keywords: Fractal dimension; High temperature; Limestone; NMR; Pore structure; Radon exhalation.

MeSH terms

  • Air Pollutants, Radioactive* / analysis
  • Construction Materials
  • Exhalation
  • Hot Temperature
  • Radiation Monitoring*
  • Radon* / analysis

Substances

  • Radon
  • Air Pollutants, Radioactive