Electrochemical and Photoelectrochemical Detection of Hydrogen Peroxide Using Cu2O/Cu Nanowires Decorated with TiO2- x Deriving from MXenes

Quan Li; Shufei Fu; Xing Wang; Liang Wang; Xin Liu; Yongsheng Gao; Qin Li; Wentai Wang

doi:10.1021/acsami.2c19531

Electrochemical and Photoelectrochemical Detection of Hydrogen Peroxide Using Cu₂O/Cu Nanowires Decorated with TiO_{2- x} Deriving from MXenes

ACS Appl Mater Interfaces. 2022 Dec 28;14(51):57471-57480. doi: 10.1021/acsami.2c19531. Epub 2022 Dec 15.

Authors

Quan Li¹, Shufei Fu¹, Xing Wang¹, Liang Wang¹, Xin Liu², Yongsheng Gao³, Qin Li⁴, Wentai Wang¹

Affiliations

¹ Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao266100, China.
² Institute for New Energy Materials and Low-Carbon Technologies, Tianjin University of Technology, Tianjin300384, China.
³ Institute for Integrated and Intelligent Systems, School of Engineering and Built Environment, Griffith University, Brisbane, Queensland4111, Australia.
⁴ Queensland Micro- and Nanotechnology Centre, School of Engineering and Built Environment, Griffith University, Nathan Campus, Brisbane, Queensland4111, Australia.

PMID: 36520600
DOI: 10.1021/acsami.2c19531

Abstract

H₂O₂ is a major transmitter of redox signals in electrochemical processes, whose detection is relevant for various industries. Herein, we developed a new fabrication method for a Cu₂O/Cu nanowire-based nonenzymatic H₂O₂ electrochemical sensor that was decorated with irregular TiO_2-x nanoparticles deriving form Ti₃C₂ MXene. The TiO_2-x/Cu₂O/Cu-NW electrodes possess excellent selectivity, stability, and reproducibility for H₂O₂ detection in both EC and PEC operational modes. In the EC detection of H₂O₂, the TiO_2-x/Cu₂O/Cu-NW electrode shows a linear relationship in the range from 10 μM to 42.19 mM and a low detection limit of 0.79 μM (S/N = 3), which has a similar sensitivity but a much broader linear range compared with the commercial H₂O₂ analyzer (0-5.88 mM, Q45H/84, US-QContums). It also shows excellent recovery in detecting H₂O₂ in the real orange juice and milk samples with the recovery ranging from 96.9 to 105%, indicating the potential for practical applications. In the PEC detection of H₂O₂, the TiO_2-x/Cu₂O/Cu-NW electrode shows a lower detection limit of 59 nM (S/N = 3), which is 13 times more sensitive than the EC electrode. The enhanced PEC performance can be attributed to the formation of p-n heterojunction between TiO_2-x and Cu₂O, which improves light utilization and inhibits the recombination of photo-induced electrons and holes. This work illuminates the extraordinary potential of MXene-derived TiO₂ in electrochemical and photoelectrochemical applications.

Keywords: Cu2O/Cu nano-wires; H2O2 sensing; MXene; TiO2−x; electrochemical; non-enzymatic; photoelectrochemical.