Currently, biomethane obtained from coal resources, such as lignite and peat, serves as a sustainable biofuel urgently needed by the energy economy. To improve biomethane yield from lignite, the effects of different concentrations of benzyl alcohol, a degraded product of humic acid, on a biomethanation fermentation system were analyzed. The total biomethane yield, daily biomethane yield, coenzyme F420, VFA (volatile fatty acids) concentration, alkalinity, and pH were used to determine the optimal benzyl alcohol concentration. The biomethanation fermentation system with 2000 mg/L benzyl alcohol produced up to 4.03 mL/g of biomethane, which was 1.15 times that produced from the control group. The coenzyme F420, VFA, alkalinity, and pH of the system after adding 2000 mg/L benzyl alcohol were more preferable after adding other concentrations during the lignite biomethanation process. In summary, 2000 mg/L benzyl alcohol had a significantly positive effect on the lignite biomethanation fermentation system. When benzyl alcohol is added to the fermentation system, it accelerates the tricarboxylic acid cycle, which in turn produces more biomethane. Additionally, the self-supply of lignite microbial transformation nutrients from the perspective of chemical composition was explored as a novel approach in solving the common problem of low biomethane yield from a single lignite raw material. This also laid a foundation for subsequent steps through the adjustment of pretreatment conditions to ensure that the lignite pretreatment liquid contained increased benzyl alcohol, and a greater yield of biomethane can be produced after activated sludge addition.
© 2022 The Authors. Published by American Chemical Society.